Syntheses, characterization and antifungal activity of tris(1,10-phenanthroline)iron(ii) bis(n-r-sulfonyldithiocarbimate)zincate(ii)

dc.contributor.authorBottega, Fernanda C.
dc.contributor.authorOliveira, Marcelo R. L.
dc.contributor.authorGarcia, Camila V.
dc.contributor.authorMenezes, Daniele C.
dc.contributor.authorRubinger, Mayura M. M.
dc.contributor.authorZambolim, Laercio
dc.date.accessioned2018-02-27T16:50:42Z
dc.date.available2018-02-27T16:50:42Z
dc.date.issued2013-05-25
dc.description.abstractFour new compounds with the general formula [Fe(phen)3][Zn(RSO2N=CS2)2], where phen = 1,10-phenanthroline, R = 4-FC6H4 (1), 4-ClC6H4 (2), 4-BrC6H4 (3) and 4-IC6H4 (4), respectively, were obtained by the reaction of the appropriate potassium N-R-sulfonyldithiocarbimate (RSO2N=CS2K2) and tris(1,10-phenanthroline)iron(II) sulfate, with zinc(II) acetate dihydrate in dimethylformamide. The elemental analyses and the IR data were consistent with the formation of the expected complexes salts. The 1H and 13C NMR spectra showed the signals for the cationic iron(II) complex and dithiocarbimate moieties. The molar conductance data were consistent with the 1:1 cation:anion complexes in 1-4. The antifungal activities of the compounds were tested in vitro against Candida albicans, Candida tropicalis and Colletotrichum gloeosporioides.en
dc.formatpdfpt-BR
dc.identifier.issn1678-7064
dc.identifier.urihttp://dx.doi.org/10.1590/S0100-40422013000600011
dc.identifier.urihttp://www.locus.ufv.br/handle/123456789/17954
dc.language.isoengpt-BR
dc.publisherQuímica Novapt-BR
dc.relation.ispartofseriesv. 36, n. 6, p.803-807, 2013pt-BR
dc.rightsOpen Accesspt-BR
dc.subjectDithiocarbimatespt-BR
dc.subjectMetal complexespt-BR
dc.subjectAntifungal activitypt-BR
dc.titleSyntheses, characterization and antifungal activity of tris(1,10-phenanthroline)iron(ii) bis(n-r-sulfonyldithiocarbimate)zincate(ii)en
dc.typeArtigopt-BR

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