Quantitative depth profile study of polyaniline films by photothermal spectroscopies

Abstract

In this study, we carried out a quantitative depth profile analysis of the optical properties of slightly and strongly doped polyaniline (PANI) films, using both photoacoustic and photopyroelectric spectroscopies. As the thermal diffusion length varies inversely to chopper modulation frequency, then at high chopping frequencies information about the sample near the surface is obtained, while at low chopping frequencies the data come from deeper within the sample. The objective of this study is to analyze how the polyaniline doping process in acidic media occurs in the polymeric chain using the photothermal techniques. The results showed that polymeric chains of the doped samples are composed of undoped regions, while polymeric chains of slightly doped samples present doped regions to a lesser degree. These conclusions are in accordance with published results in which doped PANI films exhibit a granular conductive regions in a quasi undoped matrix. In addition, the photothermal spectra showed that the doping process of PANI, in which films are dipped in hydrochloric acid solution, is more effective in the external surface of the films.