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https://locus.ufv.br//handle/123456789/21497
Tipo: | Artigo |
Título: | Liquid–liquid equilibrium of aqueous two-phase systems composed of poly(ethylene oxide) 1500 and different electrolytes ((NH4 )2SO4 , ZnSO4 and K2HPO4 ): experimental and correlation |
Autor(es): | Lemos, Leandro Rodrigues de Patrício, Pamela da Rocha Rodrigues, Guilherme Dias Carvalho, Raquel Moreira Maduro de Silva, Maria C. Hespanhol da Silva, Luis Henrique Mendes da |
Abstract: | Phase diagrams of aqueous two-phase systems composed of PEO1500 + salt (di-potassium phosphate + potassium hydroxide or ammonium sulfate or zinc sulfate) + water were determined at (283.15, 298.15, and 313.15) K. All systems produce a large two-phase region; however the influence of temperature on the binodal position seems to be very small. By analyzing the effects of ammonium sulfate or zinc sulfate, it was observed that zinc was more effective in promoting phase separation than ammonium. The consistency of the tie-line data was ascertained by applying the Othmer–Tobias correlation. In this paper, aqueous two-phase systems data for nine ternary systems are correlated by using the NRTL model and UNIFAC for the activity coefficient. The results are very satisfactory, with root mean square deviations between experimental and calculated compositions as low as 0.99 and 1.21%, respectively. However the NRTL model better represents the systems in study, when compared with UNIFAC. |
Palavras-chave: | Aqueous two-phase systems Poly(ethylene oxide) Liquid–liquid extraction NRTL UNIFAC |
Editor: | Fluid Phase Equilibria |
Tipo de Acesso: | Elsevier B.V. |
URI: | https://doi.org/10.1016/j.fluid.2011.03.001 http://www.locus.ufv.br/handle/123456789/21497 |
Data do documento: | 15-Jun-2011 |
Aparece nas coleções: | Artigos |
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artigo.pdf Until 2100-12-31 | texto completo | 376,2 kB | Adobe PDF | Visualizar/Abrir ACESSO RESTRITO |
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