Use este identificador para citar ou linkar para este item: https://locus.ufv.br//handle/123456789/21486
Tipo: Artigo
Título: Phase diagram and thermodynamic modeling of PEO + organic salts + H2O and PPO + organic salts + H2O aqueous two-phase systems
Autor(es): Patrício, Pamela da Rocha
Mageste, Aparecida Barbosa
Lemos, Leandro Rodrigues de
Carvalho, Raquel Moreira Maduro de
Silva, Luis Henrique Mendes da
Silva, Maria C. Hespanhol da
Abstract: The phase diagrams of PEO1500 + sodium tartrate + water, PPO400 + sodium tartrate + water, PEO1500 + sodium succinate + water, PPO400 + sodium succinate + water, PEO1500 + sodium citrate + water, PPO400 + sodium citrate + water and PPO400 + sodium acetate + water aqueous two-phase systems were determined at (283.15, 298.15, and 313.15) K. Both equilibrium phases composition were analyzed by conductimetry and refractive index. In this paper, the influences of polymer hydrophobicity, salt nature and temperature on the phase diagram were analyzed. The phase separation processes was endothermic and the hydrophobic increase make easier the phase splitting, while the electrolyte capacity to induce phase separation follow the order: citrate > tartrate > succinate. The consistency of the tie-line data was ascertained by applying the Othmer–Tobias correlation. The experimental data were correlated with the NRTL model for the activity coefficient, with estimation of new interaction energy parameters. The results, analyzed in terms of root mean square deviations between experimental and calculated compositions, were considered satisfactory.
Palavras-chave: Aqueous two-phase systems
Poly(ethylene oxide)
Poly(propylene oxide)
NRTL model
Editor: Fluid Phase Equilibria
Tipo de Acesso: Elsevier B.V.
URI: https://doi.org/10.1016/j.fluid.2011.02.013
http://www.locus.ufv.br/handle/123456789/21486
Data do documento: 15-Jun-2015
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